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The electronic structure and energy barrier analysis are used to identify the initial competitive scissions of C–H, N–H and C–N bonds The interaction between fragments and surface in the TS plays a decisive role in controlling the energy barrier of initial CH 3 NH 2 decomposition on Pt(111)May 14, 21 · "p u n c h i n ' t h e c l o c k" debuted and peaked at # on the Billboard Hot 100 for the charting week ending May 29, 21 6 The OffSeason (21)We measure upper limits for the bond enthalpies of the N–H and C–N bonds in HNCO by observation of photodissociation appearance thresholds for the NCO (X 2 Π) and NH (a 1 Δ) fragments from initially selected HNCO vibrational states The upper limit of the dissociation energy of the H–N bond is D 0 (H–NCO)≤1096±04 kcal/mol and that of the N–C bond is D 0

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